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Advanced diamond-reinforced metal matrix composites via cold spray: properties and deposition mechanism

机译:通过冷喷涂的高级金刚石增强金属基复合材料:性能和沉积机理

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摘要

Diamond-reinforced metal matrix composites (DMMC) have great potential for wear-resistance applications due to the superior hardness of the diamond component. Cold spray as an emerging coating technique is able to fabricate coatings or bulk materials without exceeding the material melting point, thereby significantly lowering the risk of oxidation, phase transformation, and excessive thermal residual stress. In this paper, thick DMMC coatings were deposited onto aluminum alloy substrate via cold spray of three feedstock powders: copper-clad diamond and pure copper, and their mixtures. It was found that, due to its low processing temperature, cold spray is able to prevent graphitization of the diamond in the DMMC coatings. Further to that, the original diamond phase was almost completely retained in the DMMC coatings. In case of the coatings fabricated from copper-clad diamond powders only, its mass fraction reached 43 wt.%, i.e. value higher than in any previous studies using conventional pre-mixed powders. Furthermore, it was found that the added copper content powders acted as a buffer, effectively preventing the fracture of the diamond particles in the coating. Finally, the wear test on the coatings showed that the cold sprayed DMMC coatings had excellent wear-resistance properties due to the diamond reinforcement.
机译:金刚石增强的金属基复合材料(DMMC)由于金刚石组分的优异硬度而具有很大的耐磨性潜力。冷喷涂作为一种新兴的涂层技术,能够在不超过材料熔点的情况下制造涂层或块状材料,从而显着降低了氧化,相变和过度的热残余应力的风险。在本文中,通过冷喷涂三种原料粉末:覆铜金刚石和纯铜及其混合物,将厚的DMMC涂层沉积到铝合金基材上。已经发现,由于其低的加工温度,冷喷涂能够防止DMMC涂层中金刚石的石墨化。除此之外,原始金刚石相几乎完全保留在DMMC涂层中。在仅由覆铜金刚石粉末制成的涂层的情况下,其质量分数达到43重量%,即该值高于使用常规预混合粉末的任何先前研究中的值。此外,发现添加的铜含量粉末充当缓冲剂,有效防止涂层中金刚石颗粒的破裂。最后,涂层的磨损测试表明,由于金刚石增强,冷喷涂的DMMC涂层具有出色的耐磨性。

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